| Serena Williams (USA/1) | Michelle Larcher De Brito (POR) | -:- -:- |
| Anna Tschakwetadse (RUS) | Andrea Petkovic (GER) | -:- -:- |
| Tamarine Tanasugarn (THA) | Ayumi Morita (JPN) | -:- -:- |
| Lucie Safarova (CZE/25) | Dominika Cibulkova (SVK) | -:- -:- |
| Daniela Hantuchova (SVK/24) | Vania King (USA) | -:- -:- |
| Barbora Zahlavova Strycova (CZE) | Jelena Wesnina (RUS) | -:- -:- |
| Ioana-Raluca Olaru (ROU) | Alize Cornet (FRA) | -:- -:- |
| Maria Scharapowa (RUS/16) | Anastasia Piwowarowa (RUS) | -:- -:- |
| Li Na (CHN/9) | Chanelle Scheepers (RSA) | -:- -:- |
| Mariana Duque Marino (COL) | Kurumi Nara (JPN) | -:- -:- |
| Anne Keothavong (GBR) | Anastasia Rodionova (AUS) | -:- -:- |
| Swetlana Kusnezowa (RUS/19) | Akgul Amanmuradowa (UZB) | -:- -:- |
| Sara Errani (ITA/32) | Julie Coin (FRA) | -:- -:- |
| Arantxa Parra Santonja (ESP) | Olga Goworzowa (BLR) | -:- -:- |
| Alberta Brianti (ITA) | Jill Craybas (USA) | -:- -:- |
| Agnieszka Radwanska (POL/7) | Melinda Czink (HUN) | 6:3 6:3 |
| Caroline Wozniacki (DEN/3) | Tathiana Garbin (ITA) | -:- -:- |
| Arantxa Rus (NED) | Kai Chen Chang (TPE) | -:- -:- |
| Sybille Bammer (AUT) | Roberta Vinci (ITA) | -:- -:- |
| Anastasia Pawljutschenkowa (RUS/29) | Iveta Benesova (CZE) | -:- -:- |
| Jie Zheng (CHN/23) | Pauline Parmentier (FRA) | -:- -:- |
| Sorana Cirstea (ROU) | Petra Kvitova (CZE) | -:- -:- |
| Bojana Jovanovski (SRB) | Casey Dellacqua (AUS) | -:- -:- |
| Viktoria Asarenka (BLR/14) | Mirjana Lucic (CRO) | -:- -:- |
| Flavia Pennetta (ITA/10) | Anabel Medina Garrigues (ESP) | 6:4 6:0 |
| Monica Niculescu (ROU) | Gisela Dulko (ARG) | -:- -:- |
| Yvonne Meusburger (AUT) | Klara Zakopalova (CZE) | -:- -:- |
| Aravane Rezai (FRA/18) | Magdalena Rybarikova (SVK) | -:- -:- |
| Alexandra Dulgheru (ROU/31) | Kimiko Date Krumm (JPN) | -:- -:- |
| Romina Sarina Oprandi (ITA) | Heather Watson (GBR) | -:- -:- |
| Timea Bacsinszky (SUI) | Edina Gallovits (ROU) | -:- -:- |
| Samantha Stosur (AUS/6) | Kaia Kanepi (EST) | -:- -:- |
| Kim Clijsters (BEL/8) | Maria Elena Camerin (ITA) | 6:0 6:3 |
| Karolina Sprem (CRO) | Bethanie Mattek-Sands (USA) | 6:3 6:4 |
| Shenay Perry (USA) | Anastasia Jakimowa (BLR) | 6:2 4:6 9:7 |
| Maria Kirilenko (RUS/27) | Stefanie Vögele (SUI) | 2:6 6:4 7:5 |
| Justine Henin (BEL/17) | Anastasia Sewastowa (LAT) | 6:4 6:3 |
| Kristina Barrois (GER) | Maria Koritzewa (UKR) | 6:3 6:4 |
| Yung Jan Chan (TPE) | Patty Schnyder (SUI) | 6:0 6:2 |
| Nadja Petrowa (RUS/12) | Tatjana Malek (GER) | 6:4 6:3 |
| Yanina Wickmayer (BEL/15) | Alison Riske (USA) | 6:4 5:7 6:3 |
| Kirsten Flipkens (BEL) | Stephanie Dubois (CAN) | 6:4 6:4 |
| Andrea Hlavackova (CZE) | Noppawan Lertcheewakarn (THA) | 6:3 6:2 |
| Vera Swonarewa (RUS/21) | Nuria Llagostera Vives (ESP) | 6:4 6:1 |
| Alona Bondarenko (UKR/28) | Katie O'Brien (GBR) | 6:3 6:7 (10/12) 6:4 |
| Varvara Lepchenko (USA) | Lucie Hradecka (CZE) | 6:4 7:5 |
| Aleksandra Wozniak (CAN) | Eleni Daniilidou (GRE) | 7:5 7:5 |
| Jelena Jankovic (SRB/4) | Laura Robson (GBR) | 6:3 7:6 (7/5) |
| Vera Duschewina (RUS) | Francesca Schiavone (ITA/5) | |
| Zwetana Pironkowa (BUL) | Anna Lapuschenkowa (RUS) | 6:0 7:6 (9/7) |
| Regina Kulikowa (RUS) | Melanie South (GBR) | 6:1 6:2 |
| Jaroslawa Schwedowa (KAZ/30) | Polona Hercog (SLO) | 6:1 6:4 |
| Greta Arn (HUN) | Katerina Bondarenko (UKR/34) | 7:6 (7/1) 3:6 6:3 |
| Alicia Molik (AUS) | Zuzana Kucova (SVK) | 6:2 7:5 |
| Petra Martic (CRO) | Elena Baltacha (GBR) | 2:6 7:5 6:3 |
| Marion Bartoli (FRA/11) | Julia Görges (GER) | 6:4 6:3 |
| Schahar Peer (ISR/13) | Ana Ivanovic (SRB) | 6:3 6:4 |
| Angelique Kerber (GER) | Sania Mirza (IND) | 6:4 6:1 |
| Jarmila Groth (AUS) | Renata Voracova (CZE) | 6:4 6:3 |
| Melanie Oudin (USA/33) | Anna-Lena Grönefeld (GER) | 6:3 6:0 |
| Alisa Klejbanowa (RUS/26) | Sandra Zahlavova (CZE) | 6:2 6:3 |
| Alla Kudrjawzewa (RUS) | Sofia Arvidsson (SWE) | 6:4 6:1 |
| Jekaterina Makarowa (RUS) | Agnes Szavay (HUN) | 6:4 7:6 (7/2) |
| Venus Williams (USA/2) | Rossana De Los Rios (PAR) | 6:3 6:2 |
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